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Spin Dynamics of Flavoproteins
International Journal of Molecular Sciences ( IF 5.6 ) Pub Date : 2023-05-04 , DOI: 10.3390/ijms24098218
Jörg Matysik 1 , Luca Gerhards 2 , Tobias Theiss 3 , Lisa Timmermann 3 , Patrick Kurle-Tucholski 1 , Guzel Musabirova 1 , Ruonan Qin 1 , Frank Ortmann 4 , Ilia A Solov'yov 2, 5, 6 , Tanja Gulder 3
Affiliation  

This short review reports the surprising phenomenon of nuclear hyperpolarization occurring in chemical reactions, which is called CIDNP (chemically induced dynamic nuclear polarization) or photo-CIDNP if the chemical reaction is light-driven. The phenomenon occurs in both liquid and solid-state, and electron transfer systems, often carrying flavins as electron acceptors, are involved. Here, we explain the physical and chemical properties of flavins, their occurrence in spin-correlated radical pairs (SCRP) and the possible involvement of flavin-carrying SCRPs in animal magneto-reception at earth’s magnetic field.

中文翻译:

黄素蛋白的自旋动力学

这篇简短的综述报告了化学反应中发生的令人惊讶的核超极化现象,如果化学反应是光驱动的,则称为 CIDNP(化学诱导动态核极化)或光 CIDNP。这种现象发生在液态和固态中,并且涉及通常携带黄素作为电子受体的电子转移系统。在这里,我们解释了黄素的物理和化学性质、它们在自旋相关自由基对 (SCRP) 中的出现以及携带黄素的 SCRP 可能参与地球磁场中的动物磁接收。
更新日期:2023-05-04
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