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Wide Bandgap Polymer Donors Containing Dihalovinyl Thiophene Building Blocks for Organic Solar Cells Macromolecules (IF 5.5) Pub Date : 2024-05-16 Yi Yuan, Songbo Cui, Xu Li, Haitao Liu, Jinliang Wang, Yuning Li
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Disclosing Solid-Phase-Transition Mechanism from Nonpolar to Polar Poly(vinylidene fluoride) via In Situ Real-Space Visual Methods Macromolecules (IF 5.5) Pub Date : 2024-05-16 Haikuo Li, Mingxiang Li, Mengling Liu, Bin Wei, Shouke Yan, Xiaoli Sun
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Six Atom Elongated Radical Polymerization Enabled by 1,5-Hydrogen Atom Transfer Macromolecules (IF 5.5) Pub Date : 2024-05-16 Yuyu Chen, Chaowei Yue, Bang An, Shuai Liu, Litao Zhou, Chong-Lei Ji, Yifan Li
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Controlling Hydrophobicity of Colloidal Silica to Promote Miscibility in Polymer Nanocomposites Macromolecules (IF 5.5) Pub Date : 2024-05-16 Marshall C. Tekell, Kewei Wu, Eric G. Keeler, Nicholas F. Mendez, Jingchao Qin, Yipeng Zhang, Bridgie Cawthon
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Anisotropic and Non-Gaussian Diffusion of Thin Nanorods in Polymer Networks Macromolecules (IF 5.5) Pub Date : 2024-05-16 Yulong Chen, Zhijun Xiang, Haozhe Ren, Fengqin Guo, Venkat Ganesan, Jun Liu
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Structural, Solvent Quality Changes and Flow Regulation through PEO-Grafted Gold Nanopore Macromolecules (IF 5.5) Pub Date : 2024-05-15 Guang Chen
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The Dynamic Interplay of Cross-Linking and Exchange Reaction Probabilities during Vitrimer Synthesis: A Monte Carlo Approach Macromolecules (IF 5.5) Pub Date : 2024-05-15 Jie Liu, Jie Jin, Robert Conka, Paul H. M. Van Steenberge, Dagmar R. D’hooge, Zheng-Hong Luo, Yin-Ning Zhou
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Effect of Block Copolymer Self-Assembly on Phase Separation in Photopolymerizable Epoxy Blends Macromolecules (IF 5.5) Pub Date : 2024-05-15 Tanner L. Grover, C. Allan Guymon
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Deep Insight into the Effect of Microstructure Evolution on Film-Forming Properties of Polylactide during Uniaxial Hot-Stretching Process Macromolecules (IF 5.5) Pub Date : 2024-05-15 Bingbing Zeng, Jinxiang Ai, Mingxin Xia, Yucen Pang, Yu Zheng, Jiabin Shen, Shaoyun Guo
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Dissipative Particle Dynamics Simulation Plus Slip-Springs for Entangled Polymers with Various Slip-Spring Densities Macromolecules (IF 5.5) Pub Date : 2024-05-15 Yuichi Masubuchi, Hongxia Guo, Fan Wang, Bamin Khomami, Mahdi Boudaghi-Khajehnobar, Yuya Doi, Takato Ishida, Takashi Uneyama
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Enhancing Aqueous Reversible Addition–Fragmentation Chain Transfer Photopolymerization in Continuous Flow Reactors with Hairy Hollow Conjugated Microporous Polymer Nanocomposites Macromolecules (IF 5.5) Pub Date : 2024-05-15 Yuan Huang, Qian Xiang, Xue Li, Tao Cai
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Anionic or Radical Polymerization Catalyzed by Metal Triflate-Based Lewis Pairs: A Comprehensive Mechanistic Study Macromolecules (IF 5.5) Pub Date : 2024-05-15 Riki Akita, Mayo Horibe, Katsuhiro Yamamoto, Shin-ichi Matsuoka
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Improving the performance of acrylic-epoxy ester hybrid coatings with phosphate monomers Polym. Chem. (IF 4.6) Pub Date : 2024-05-16 Xiaomei Wang, Mike Tebyetekerwa, Yujian Chen, Xin Sun, Weiwei Cong, Xiao Wang, Lizhuang Chen, Z. L. Li, Taijiang Gui, Weili Li
There is a growing interest in environmentally friendly coatings from the paint and coating industries, with water-borne acrylic-epoxy ester hybrid resins emerging as a prominent candidate. Despite their eco-friendliness, these resins exhibit poor mechanical and anti-corrosion properties. These two essential properties can be improved by grafting new functional materials into the hybrid resin. In this
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Segmental Mobility in Linear Polylactides of Various Molecular Weights Polymer (IF 4.6) Pub Date : 2024-05-16 Panagiotis A. Klonos, Nikolaos D. Bikiaris, Panagiotis Barmpalexis, Apostolos Kyritsis
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Anionic Conjugate Addition Oligomerization of Carbon Dioxide/Butadiene Derived Lactones ACS Macro Lett. (IF 5.8) Pub Date : 2024-05-15 Brennan J. Crawford, Calum Bochenek, Luis D. Garcia Espinosa, Addie R. Keating, Kayla Williams-Pavlantos, Chrys Wesdemiotis, James M. Eagan
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A proof-of-concept study on a fully biobased and degradable polymer network based on vanillin and myrcene Polym. Chem. (IF 4.6) Pub Date : 2024-05-15 Pia S. Löser, Arthur Lamouroux, Michael A. R. Meier, Audrey Llevot
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Tunable multicolor fluorescence of polyurethane derivatives controlled by molecular weight Polym. Chem. (IF 4.6) Pub Date : 2024-05-15 Ke-Xin Li, Ya-Jie Meng, Chang-Yi Zhu, Nan Jiang, Jia-Wei Xu, Yan-Hong Xu
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Novel thermal initiator systems for radical induced cationic frontal polymerization Polym. Chem. (IF 4.6) Pub Date : 2024-05-15 David Bassenheim, Moritz Mitterbauer, Robert Liska, Patrick Knaack
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Radical decarboxylation: an emerging tool in polymer synthesis Polym. Chem. (IF 4.6) Pub Date : 2024-05-13 Chima Anyaegbu, Gianluca Vidali, Darsan Haridas, Joel F. Hooper
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Stereoselective ring-opening polymerization of rac-lactide catalyzed by the proton sponge bisphosphazene 1,8-bis(hexamethyltriaminophosphazenyl)naphthalene Polym. Chem. (IF 4.6) Pub Date : 2024-05-10 Zhenqing Zhang, Xiaoyu Guo, Xinhui Kou, Na Zhao, Zhibo Li
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Framework for a High-Throughput Screening Method to Assess Polymer/Plasticizer Miscibility: The Case of Hydrocarbons in Polyolefins Macromolecules (IF 5.5) Pub Date : 2024-05-14 Lois Smith, Hossein Ali Karimi-Varzaneh, Sebastian Finger, Giuliana Giunta, Alessandro Troisi, Paola Carbone
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Nonmonotonic Composition Dependence of Viscosity upon Adding Single-Chain Nanoparticles to Entangled Polymers Macromolecules (IF 5.5) Pub Date : 2024-05-14 Christina Pyromali, Nikolaos Patelis, Marta Cutrano, Mounika Gosika, Emmanouil Glynos, Angel J. Moreno, Georgios Sakellariou, Jan Smrek, Dimitris Vlassopoulos
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Effects of ortho Functional Groups on the Thermo-Oxidative Cross-Linking Process and Gas Separation Properties of Phenolphthalein-Based Polyimides Macromolecules (IF 5.5) Pub Date : 2024-05-14 Xuefeng Cheng, Bo Chen, Guoke Zhao, Gongqing Tang, Peiyong Qin, Yiqun Liu, Pei Li
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Influence of Chemical Side Groups Containing Aromatic Rings: Flow-Induced Friction Enhancement or Reduction Macromolecules (IF 5.5) Pub Date : 2024-05-14 Yiming Zhong, Shuang Liu, Longbo Luo, Qian Huang
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Structural Analysis of the Linear Elasticity of End-Cross-Linked Star Elastomers with a Number of Trapped Entanglements via Coarse-Grained Molecular Dynamics Simulations Macromolecules (IF 5.5) Pub Date : 2024-05-13 Yusuke Yasuda, Hiroshi Morita
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Three-Dimensional Orientation of a Crystalline Polymer via Epitaxial Growth from a Magnetically Oriented Nucleating Agent Macromolecules (IF 5.5) Pub Date : 2024-05-13 Ryosuke Kusumi, Sachi Teranishi, Kayoko Kobayashi, Masahisa Wada, Fumiko Kimura, Tsunehisa Kimura
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Catalyst-Free Multicomponent Polymerization of Aldehyde, Amine and Trimethylsilyl Cyanide toward Poly(α-aminonitrile)s Polym. Chem. (IF 4.6) Pub Date : 2024-05-13 Tianyu Cheng, Huadong Wang, Jianqing Ding, Junguo Fang, Jia Wang, Mingzhao Li, Jie Chen, Anjun Qin, Ben-Zhong Tang
The development of a facile and efficient multicomponent polymerization (MCP) to prepare functional polymers is of vital importance and highly desired. In this work, a MCP of dialdehydes, diamines and trimethylsilyl cyanide for the efficient preparation of cyano-containing polymers poly(α-aminonitrile)s was established, which readily produced soluble poly(α-aminonitrile)s with high weight-average molecular
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Tuning the nanoparticles internal structure: fluorinated single-chain nanoparticles (SCNPs) generated by chain collapse of random copolymers Polym. Chem. (IF 4.6) Pub Date : 2024-05-13 Marah Alqaisi, Justus Friedrich Fridrich Thümmler, Florian Lehmann, Franz-Josef Schmitt, Leonie Lentz, Fabian Rieder, Dariush Hinderberger, Wolfgang H. Binder
The generation of nanosized compartments in single chain nanoparticles (SCNPs) is a promising approach to generate individualized confinement-zones on a small scale for drug-encapsulation or catalysis. We here report the synthesis and characterization of compartmented, fluorinated SCNPs generated by single-chain collapse of amphiphilic copolymers. Polyethylene glycol (PEG) functionalized monomers were
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Highly Stretchable and Aqueous Solution-Stable Poly(3,4-ethylenedioxythiophene) Doped with Elastomeric Sulfonated-SEBS Polym. Chem. (IF 4.6) Pub Date : 2024-05-13 Yuhka Uda, Peikai Zhang, Jadranka Travas-Sejdic
The field of wearable and implantable bioelectronics is rapidly emerging for biological sensing, medical monitoring and treatment. Among the conducting polymers, poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT:PSS) stands out as a widely studied and commercially available material extensively employed in flexible bioelectronic applications. Nonetheless, PEDOT:PSS exhibits restricted
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Multifunctional inorganic-organic phase-change hydrogel with excellent light-to-thermal energy conversion and strain sensing capabilities for medical thermotherapy and monitoring Polymer (IF 4.6) Pub Date : 2024-05-13 Yongsheng Li, Xiao Wu, Yujie Liao, Hong Shao, Yongqian Chen, Wenbin Yang, Pengfei Lv, Yuanlin Zhou, Changyu Tang
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Effect of mechanical stretching and low amount of silica adding on gas transport properties of poly(butylene succinate-co-adipate) films. Polymer (IF 4.6) Pub Date : 2024-05-13 Mathurin Prieur, Guillaume Sudre, Fabrice Gouanvé, René Fulchiron, Eliane Espuche
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Position-Dependent Segmental Relaxation in Bottlebrush Polymers Macromolecules (IF 5.5) Pub Date : 2024-05-11 Karin J. Bichler, Bruno Jakobi, Alice Klapproth, Richard A. Mole, Gerald J. Schneider
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Zinc Catalyst for Chemical Upcycling of PLA Wastes: Novel Industrial Monomer Resource toward Poly(ester–amide) Macromolecules (IF 5.5) Pub Date : 2024-05-11 Shuang Liu, Li Hu, Jiaoyu Liu, Zisheng Zhang, Hongyi Suo, Yusheng Qin
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Asymmetric Aldol Reactions Catalyzed by Polymeric Self-Assembly with Side-Chain Dipeptide Pendants ACS Macro Lett. (IF 5.8) Pub Date : 2024-05-09 Tamanna Mallick, Debgopal Jana, Alakesh Bisai, Priyadarsi De
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Unprecedented associative exchange in CO2-sourced cyclic S,O-acetals based covalent adaptable networks Polym. Chem. (IF 4.6) Pub Date : 2024-05-10 Stephan Maes, Thomas Habets, Susanne M. Fischer, Bruno Grignard, Christophe Detrembleur, Filip E. Du Prez
New dynamic chemistries are nowadays sought to widen the library of accessible covalent adaptable networks (CANs). Here, we investigate the dynamic nature of CO2-sourced cyclic S,O-acetal bonds in unexplored conditions. Model molecule studies were conducted on various compounds and supported by extensive DFT calculations to understand the required conditions for triggering exchange and the underlying
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From health supplement to versatile monomer: Radical ring-opening polymerization and depolymerization of α-lipoic acid Polymer (IF 4.6) Pub Date : 2024-05-11 Kaitlin R. Albanese, Javier Read de Alaniz, Craig J. Hawker, Christopher M. Bates
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Multicolor Room-Temperature Phosphorescence Achieved by Intrinsic Polymers Containing Solely One Phosphor Unit Macromolecules (IF 5.5) Pub Date : 2024-05-10 Jiayue Huang, Lunjun Qu, Liang Gao, Xiaojuan Wang, Qingao Chen, Yongkang Wang, Ying Zhu, Chen Li, Youbing Li, Chaolong Yang
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Soluble Polyimides Containing Benzocyclobutene Moieties: Synthesis, Cross-Linking Behavior, and Physical and Gas Transport Properties Macromolecules (IF 5.5) Pub Date : 2024-05-10 Kai Geng, Tengyao Xue, Xiaodan Li, Haoqi Sang, Shichao Feng, Chenyi Wang, Hanli Wang, Yongbing Zhuang
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Effect of Monomer Sequence Distribution on the Glass Transition Temperature of Poly(d,l-lactic-co-glycolic acid) (PLGA) Macromolecules (IF 5.5) Pub Date : 2024-05-10 Samruddhi M. Patil, You-Yeon Won
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Decoupling the Effects of Charge Density and Hydrophobicity on the Phase Behavior and Viscoelasticity of Complex Coacervates Macromolecules (IF 5.5) Pub Date : 2024-05-10 Isaac A. Ramírez Marrero, Luke Boudreau, Weiguo Hu, Rainer Gutzler, Nadine Kaiser, Bernhard von Vacano, Rupert Konradi, Sarah L. Perry
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High Vertical Hole Mobility through Minimization of Water-Induced Traps by F4TCNQ Doping in Conjugated Amphiphilic Diblock Copolymers Macromolecules (IF 5.5) Pub Date : 2024-05-10 Philgon Kim, Eun Young Kim, Se Gyo Han, Minyoung Jeong, Kilwon Cho, Jin Kon Kim
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Counter Anion Type Influences the Glass Transition Temperature of Polyelectrolyte Complexes Macromolecules (IF 5.5) Pub Date : 2024-05-09 Suvesh Manoj Lalwani, Kayla Hellikson, Piotr Batys, Jodie L. Lutkenhaus
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Full-Color-Tunable and pH-Responsive Ultralong Afterglow Based on a Single Polymeric Phosphor with Triple-Mode Delayed Emission Macromolecules (IF 5.5) Pub Date : 2024-05-09 Yongkang Zuo, Hongjun Yang, Yiye Song, Wenyan Huang, Qimin Jiang, Li Jiang, Bibiao Jiang, Guangzhao Zhang
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Helix-Sense-Selective Permeation of Racemic Helical Oligoacetylenes through One-Handed Helical Channels in Polymer Membranes ACS Macro Lett. (IF 5.8) Pub Date : 2024-05-06 Shuaishuai Huang, Ken-ichi Shinohara, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
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Photocurable acylhydrazone covalent adaptable networks with fast dynamic exchange and tunable viscoelastic properties Polym. Chem. (IF 4.6) Pub Date : 2024-05-10 Yunsheng Xu, Chonglin Liu, Yanying Zhao, Xianming Zhang, Minna Hakkarainen
Acylhydrazone linkages are appealing for design of covalent adaptable networks (CANs) due to the reversible nature and ease of formation from readily available starting materials. However, acylhydrazone CANs typically exhibit dynamic behavior within a limited temperature range due to their slow exchange rate. Here, vanillin was modified by a two-step reaction involving allylation and imination, followed
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Kinetic control in the synthesis of highly conductive solution-processable PEDOTs Polym. Chem. (IF 4.6) Pub Date : 2024-05-05 Ziyi Guo, Jingming Tang, Jingyuan Yao, Yuda Li
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High performance multifunctional piezoelectric PAN/UiO-66-NO2/MXene composite nanofibers for flexible touch sensor Polymer (IF 4.6) Pub Date : 2024-05-10 Qianbing Lin, Sixian Chen, Yan Huang, Hao Wang, Yibo Wu, Yushun Jin, Ruofan Liu, Qisong Shi, Yongri Liang
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Synthesis and preparation of thermoplastic silicone elastomer and molecular dynamics simulation of self healing and mechanical properties Polymer (IF 4.6) Pub Date : 2024-05-10 Fan Fei, Xin Chai, Wanying Hu, Wentong Lu, Hao Tian, Jincheng Wang
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Innovative porous organic polymer incorporating ferrocene and s-triazine: An effective method for converting nitroarenes to benzimidazoles using visible light Polymer (IF 4.6) Pub Date : 2024-05-10 Mohammad Bashiri, Tianjian Zhang, Yanlong Gu, Mona Hosseini-Sarvari
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Molecular Dynamics Simulation of In Situ Polymerization: Chain Conformation Transition Macromolecules (IF 5.5) Pub Date : 2024-05-08 Siyu Chen, Jingyuan Sun, Wei Chen, Ying Ren, Jingdai Wang, Yongrong Yang
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Bridging of Poly(Acetylene)s and PEG-Modified Poly(Olefin)s Through Ring-Opening Metathesis Copolymerization (ROMCP) Polym. Chem. (IF 4.6) Pub Date : 2024-05-09 Santhosh Kumar Podiyanachari, Maciej Barłóg, Mohammed Al-Hashimi, Hassan S. Bazzi
Amphiphilic copolymers of highly conjugated poly(acetylene)s and poly(ethylene glycol)-functionalized perylene diimide (PEG750-PDI)-incorporated poly(olefin)s have been synthesized via one-pot tandem cyclopolymerization and ring-opening metathesis copolymerization (ROMCP) methodologies. Both di- and tri-block copolymers were prepared as regular-block and random-block copolymers from 1,6-heptadiyne
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Recyclable elastomers with high mechanical performance and vibration-damping property via triple dynamic bonds Polymer (IF 4.6) Pub Date : 2024-05-09 Yujia Hou, Haitao Wu, Qi Wu, Jinrong Wu
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An in situ strategy to produce high-performance composite thermal adhesives with excellent bonding, thermal transfer and adjustable electrical performance based on a designer hyperbranched epoxy copolymer Polymer (IF 4.6) Pub Date : 2024-05-09 Ruotong Lan, Jinwei Song, Yanbo Wang, Yanan Tao, Huijian Ye, Mingxing An, Weili Yan, Yufei Li, Wenbin Zhang, Feng Li, Lixin Xu
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Assessment of properties of bamboo fiber and EPDM reinforced polypropylene microcellular foam composites Polymer (IF 4.6) Pub Date : 2024-05-09 Wei Guo, Jialong Zhao, Feng Zhao, Tao Feng, Lian Liu
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Effect of Cross-Link Homogeneity on the High-Strain Behavior of Elastic Polymer Networks Macromolecules (IF 5.5) Pub Date : 2024-05-08 Victoria A. Kong, Thomas A. Staunton, Jennifer E. Laaser
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One-Pot Four-Component Synthesis of Acid-Responsive and Degradable Heterochain Polymers with Nonconventional Luminescence Macromolecules (IF 5.5) Pub Date : 2024-05-08 Fenggang Chen, Dongyang Fan, Dong Wang, Ting Han, Ben Zhong Tang
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Electrochemical Postfunctionalization of Thiophene–Fluorene Alternating Copolymers via Anodic C–H Phosphonylation Macromolecules (IF 5.5) Pub Date : 2024-05-08 Kohei Taniguchi, Tomoyuki Kurioka, Kosuke Sato, Ikuyoshi Tomita, Shinsuke Inagi
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Interrogating Cocrystallization and Microphase Segregation in Meticulously Engineered Rod–Rod Poly(thieno)thiophene-Based Block Copolymers for Organic Field-Effect Transistors Macromolecules (IF 5.5) Pub Date : 2024-05-08 Qingqing Zhao, Hao Zheng, Dingke Li, Juan Peng
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Correction to “Effect of Polymer Composition and Morphology on Mechanochemical Activation in Nanostructured Triblock Copolymers” Macromolecules (IF 5.5) Pub Date : 2024-05-07 Zijian Huo, Swati Arora, Victoria A. Kong, Brandon J. Myrga, Antonia Statt, Jennifer E. Laaser
In the original article, (1) the Acknowledgment incorrectly failed to recognize funding from NSF award number DMR-2143864. The corrected Acknowledgment is This work was supported by the National Science Foundation (DMR-1846665, Z.H., S.A., V.A.K., B.J.M., and J.E.L., and DMR-2143864, A.S.). The authors also thank Missy L. Hazen at Penn State Microscopy Facility, University Park, PA, for providing services
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Continuous Flow Synthesis of Functional Isocyanate-Free Poly(oxazolidone)s by Step-Growth Polymerization ACS Macro Lett. (IF 5.8) Pub Date : 2024-05-08 Fabiana Siragusa, Lionel Crane, Pierre Stiernet, Thomas Habets, Bruno Grignard, Jean-Christophe M. Monbaliu, Christophe Detrembleur